Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes
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2014
Authors
Glavaški, Olivera S.Petrović, Slobodan D.
Mijin, Dušan Z.
Jovanović, Mića B.
Dugandzić, A. M.
Zeremski, Tijana
Avramov-Ivić, Milka
Article (Published version)
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For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.
Keywords:
Cyclic voltammetry / Liquid chromatography / Electrolysis / Liquid mass spectroscopySource:
Electroanalysis, 2014, 26, 9, 1877-1880Publisher:
- Wiley-V C H Verlag Gmbh, Weinheim
Funding / projects:
- Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-MESTD-Basic Research (BR or ON)-172013)
DOI: 10.1002/elan.201400249
ISSN: 1040-0397
WoS: 000343926700001
Scopus: 2-s2.0-84908205713
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FiVeRTY - JOUR AU - Glavaški, Olivera S. AU - Petrović, Slobodan D. AU - Mijin, Dušan Z. AU - Jovanović, Mića B. AU - Dugandzić, A. M. AU - Zeremski, Tijana AU - Avramov-Ivić, Milka PY - 2014 UR - http://fiver.ifvcns.rs/handle/123456789/1316 AB - For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes. PB - Wiley-V C H Verlag Gmbh, Weinheim T2 - Electroanalysis T1 - Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes EP - 1880 IS - 9 SP - 1877 VL - 26 DO - 10.1002/elan.201400249 ER -
@article{ author = "Glavaški, Olivera S. and Petrović, Slobodan D. and Mijin, Dušan Z. and Jovanović, Mića B. and Dugandzić, A. M. and Zeremski, Tijana and Avramov-Ivić, Milka", year = "2014", abstract = "For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.", publisher = "Wiley-V C H Verlag Gmbh, Weinheim", journal = "Electroanalysis", title = "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes", pages = "1880-1877", number = "9", volume = "26", doi = "10.1002/elan.201400249" }
Glavaški, O. S., Petrović, S. D., Mijin, D. Z., Jovanović, M. B., Dugandzić, A. M., Zeremski, T.,& Avramov-Ivić, M.. (2014). Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis Wiley-V C H Verlag Gmbh, Weinheim., 26(9), 1877-1880. https://doi.org/10.1002/elan.201400249
Glavaški OS, Petrović SD, Mijin DZ, Jovanović MB, Dugandzić AM, Zeremski T, Avramov-Ivić M. Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis. 2014;26(9):1877-1880. doi:10.1002/elan.201400249 .
Glavaški, Olivera S., Petrović, Slobodan D., Mijin, Dušan Z., Jovanović, Mića B., Dugandzić, A. M., Zeremski, Tijana, Avramov-Ivić, Milka, "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes" in Electroanalysis, 26, no. 9 (2014):1877-1880, https://doi.org/10.1002/elan.201400249 . .