Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes
Само за регистроване кориснике
2014
Аутори
Glavaški, Olivera S.Petrović, Slobodan D.
Mijin, Dušan Z.
Jovanović, Mića B.
Dugandzić, A. M.
Zeremski, Tijana
Avramov-Ivić, Milka
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.
Кључне речи:
Cyclic voltammetry / Liquid chromatography / Electrolysis / Liquid mass spectroscopyИзвор:
Electroanalysis, 2014, 26, 9, 1877-1880Издавач:
- Wiley-V C H Verlag Gmbh, Weinheim
Финансирање / пројекти:
- Проучавање синтезе, структуре и активности органских једињења природног и синтетског порекла (RS-MESTD-Basic Research (BR or ON)-172013)
DOI: 10.1002/elan.201400249
ISSN: 1040-0397
WoS: 000343926700001
Scopus: 2-s2.0-84908205713
Колекције
Институција/група
FiVeRTY - JOUR AU - Glavaški, Olivera S. AU - Petrović, Slobodan D. AU - Mijin, Dušan Z. AU - Jovanović, Mića B. AU - Dugandzić, A. M. AU - Zeremski, Tijana AU - Avramov-Ivić, Milka PY - 2014 UR - http://fiver.ifvcns.rs/handle/123456789/1316 AB - For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes. PB - Wiley-V C H Verlag Gmbh, Weinheim T2 - Electroanalysis T1 - Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes EP - 1880 IS - 9 SP - 1877 VL - 26 DO - 10.1002/elan.201400249 ER -
@article{ author = "Glavaški, Olivera S. and Petrović, Slobodan D. and Mijin, Dušan Z. and Jovanović, Mića B. and Dugandzić, A. M. and Zeremski, Tijana and Avramov-Ivić, Milka", year = "2014", abstract = "For the first time the electrochemical degradation of the pesticide dimethenamid-P was studied. Its direct electrochemical degradation, using potential cycling at a gold electrode, was performed by cyclic voltammetry and HPLC analysis of electrolyte after 72 h showed 56.8% of degradation. HPLC-MS indicates the formation of degradation products through the elimination of chlorine atom and C-N bond cleavage. By indirect electrolysis using DSA Ti/PtOx and DSA Ti/RuO2 electrodes during 30 minutes 87.2% and 88.3% of dimethenamid-P was degradated, respectively. The high percentage of degradation of dimethenamid-P was achieved with non time consuming, simple and cheap electrochemical processes.", publisher = "Wiley-V C H Verlag Gmbh, Weinheim", journal = "Electroanalysis", title = "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes", pages = "1880-1877", number = "9", volume = "26", doi = "10.1002/elan.201400249" }
Glavaški, O. S., Petrović, S. D., Mijin, D. Z., Jovanović, M. B., Dugandzić, A. M., Zeremski, T.,& Avramov-Ivić, M.. (2014). Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis Wiley-V C H Verlag Gmbh, Weinheim., 26(9), 1877-1880. https://doi.org/10.1002/elan.201400249
Glavaški OS, Petrović SD, Mijin DZ, Jovanović MB, Dugandzić AM, Zeremski T, Avramov-Ivić M. Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes. in Electroanalysis. 2014;26(9):1877-1880. doi:10.1002/elan.201400249 .
Glavaški, Olivera S., Petrović, Slobodan D., Mijin, Dušan Z., Jovanović, Mića B., Dugandzić, A. M., Zeremski, Tijana, Avramov-Ivić, Milka, "Electrochemical Degradation of the Pesticide Dimethenamid-P at Gold, DSA Platinum and Ruthenium Oxide Electrodes in Different Electrolytes" in Electroanalysis, 26, no. 9 (2014):1877-1880, https://doi.org/10.1002/elan.201400249 . .