Characterization of films based on cellulose acetate/poly(caprolactone diol) intended for active packaging prepared by green chemistry principles
Аутори
Erceg, TamaraVukić, Nevena
Šovljanski, Olja
Stupar, Alena
Šergelj, Vanja
Aćimović, Milica
Baloš, Sebastian
Ugarković, Jovana
Šuput, Danijela
Popović, Senka
Rakić, Srđan
Чланак у часопису (Рецензирана верзија)
Метаподаци
Приказ свих података о документуАпстракт
Biodegradable active packaging films based on a cellulose acetate and poly(caprolactone diol) blend with incorporated lemongrass oil were developed. Films were prepared using a novel bio-based plasticizer, glycerol tritartarate, synthesized using the principles of green chemistry. The influence of the plasticizer, as well as the essential oil amount, on the structural, surface, mechanical, and thermal properties of the blend was investigated. The plasticizer was shown to work as a compatibilizer for two polymers, according to the results of scanning electron microscopy and surface energy analysis. Blends with a greater amount of plasticizer possessed better mechanical properties but showed worse resistance to water. The antimicrobial property of the blend with lemongrass oil was found to be superior to that of the blend without essential oil. The incorporation of lemongrass oil into the polymer blend resulted in one more step longer thermal degradation process. The optimal film propert...ies, biodegradability, cost-effective preparation method, and additional functions made these films suitable for the production of packaging for grapefruit.
Кључне речи:
cellulose acetate / poly(caprolactone diol) / glycerol tritartarate / lemongrass oil / blends / biodegradable active packaging / torsion resistanceИзвор:
ACS Sustainable Chemistry & Engineering, 2022, 10, 28, 9141-9154Издавач:
- Washington : American Chemical Society (ACS)
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200134 (Универзитет у Новом Саду, Технолошки факултет) (RS-MESTD-inst-2020-200134)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200222 (Институт за прехрамбене технологије, Нови Сад) (RS-MESTD-inst-2020-200222)
Напомена:
- This peer-reviewed accepted version of the article will be available in open access on 15 July 2023. The published article available at the publisher https://pubs.acs.org/doi/10.1021/acssuschemeng.2c02009
Повезане информације:
- Друга верзија
http://fiver.ifvcns.rs/handle/123456789/2875
Колекције
Институција/група
FiVeRTY - JOUR AU - Erceg, Tamara AU - Vukić, Nevena AU - Šovljanski, Olja AU - Stupar, Alena AU - Šergelj, Vanja AU - Aćimović, Milica AU - Baloš, Sebastian AU - Ugarković, Jovana AU - Šuput, Danijela AU - Popović, Senka AU - Rakić, Srđan PY - 2022 UR - http://fiver.ifvcns.rs/handle/123456789/2876 AB - Biodegradable active packaging films based on a cellulose acetate and poly(caprolactone diol) blend with incorporated lemongrass oil were developed. Films were prepared using a novel bio-based plasticizer, glycerol tritartarate, synthesized using the principles of green chemistry. The influence of the plasticizer, as well as the essential oil amount, on the structural, surface, mechanical, and thermal properties of the blend was investigated. The plasticizer was shown to work as a compatibilizer for two polymers, according to the results of scanning electron microscopy and surface energy analysis. Blends with a greater amount of plasticizer possessed better mechanical properties but showed worse resistance to water. The antimicrobial property of the blend with lemongrass oil was found to be superior to that of the blend without essential oil. The incorporation of lemongrass oil into the polymer blend resulted in one more step longer thermal degradation process. The optimal film properties, biodegradability, cost-effective preparation method, and additional functions made these films suitable for the production of packaging for grapefruit. PB - Washington : American Chemical Society (ACS) T2 - ACS Sustainable Chemistry & Engineering T1 - Characterization of films based on cellulose acetate/poly(caprolactone diol) intended for active packaging prepared by green chemistry principles EP - 9154 IS - 28 SP - 9141 VL - 10 DO - 10.1021/acssuschemeng.2c02009 ER -
@article{ author = "Erceg, Tamara and Vukić, Nevena and Šovljanski, Olja and Stupar, Alena and Šergelj, Vanja and Aćimović, Milica and Baloš, Sebastian and Ugarković, Jovana and Šuput, Danijela and Popović, Senka and Rakić, Srđan", year = "2022", abstract = "Biodegradable active packaging films based on a cellulose acetate and poly(caprolactone diol) blend with incorporated lemongrass oil were developed. Films were prepared using a novel bio-based plasticizer, glycerol tritartarate, synthesized using the principles of green chemistry. The influence of the plasticizer, as well as the essential oil amount, on the structural, surface, mechanical, and thermal properties of the blend was investigated. The plasticizer was shown to work as a compatibilizer for two polymers, according to the results of scanning electron microscopy and surface energy analysis. Blends with a greater amount of plasticizer possessed better mechanical properties but showed worse resistance to water. The antimicrobial property of the blend with lemongrass oil was found to be superior to that of the blend without essential oil. The incorporation of lemongrass oil into the polymer blend resulted in one more step longer thermal degradation process. The optimal film properties, biodegradability, cost-effective preparation method, and additional functions made these films suitable for the production of packaging for grapefruit.", publisher = "Washington : American Chemical Society (ACS)", journal = "ACS Sustainable Chemistry & Engineering", title = "Characterization of films based on cellulose acetate/poly(caprolactone diol) intended for active packaging prepared by green chemistry principles", pages = "9154-9141", number = "28", volume = "10", doi = "10.1021/acssuschemeng.2c02009" }
Erceg, T., Vukić, N., Šovljanski, O., Stupar, A., Šergelj, V., Aćimović, M., Baloš, S., Ugarković, J., Šuput, D., Popović, S.,& Rakić, S.. (2022). Characterization of films based on cellulose acetate/poly(caprolactone diol) intended for active packaging prepared by green chemistry principles. in ACS Sustainable Chemistry & Engineering Washington : American Chemical Society (ACS)., 10(28), 9141-9154. https://doi.org/10.1021/acssuschemeng.2c02009
Erceg T, Vukić N, Šovljanski O, Stupar A, Šergelj V, Aćimović M, Baloš S, Ugarković J, Šuput D, Popović S, Rakić S. Characterization of films based on cellulose acetate/poly(caprolactone diol) intended for active packaging prepared by green chemistry principles. in ACS Sustainable Chemistry & Engineering. 2022;10(28):9141-9154. doi:10.1021/acssuschemeng.2c02009 .
Erceg, Tamara, Vukić, Nevena, Šovljanski, Olja, Stupar, Alena, Šergelj, Vanja, Aćimović, Milica, Baloš, Sebastian, Ugarković, Jovana, Šuput, Danijela, Popović, Senka, Rakić, Srđan, "Characterization of films based on cellulose acetate/poly(caprolactone diol) intended for active packaging prepared by green chemistry principles" in ACS Sustainable Chemistry & Engineering, 10, no. 28 (2022):9141-9154, https://doi.org/10.1021/acssuschemeng.2c02009 . .