A simple and rapid electrochemical sensing method for metribuzin determination in tap and river water samples
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2016
Authors
Stojanović, Zorica
Đurović, Ana

Kravić, Snežana

Grahovac, Nada

Suturović, Zvonimir

Bursić, Vojislava
Vuković, Gorica
Brezo, Tanja
Article (Published version)

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This paper describes an electroanalytical method for the determination of metribuzin using a thin film mercury electrode by chronopotentiometry. Research included optimization of the most important parameters of chronopotentiometric analysis and the best responses were achieved in Britton-Robinson buffer at pH 5.0, using an initial potential of -0.21 V, ending potential of -1.1 V, and reduction current in the range from -4 mu A to -15 mA. Under these conditions, metribuzin was reduced in an irreversible electrode reaction process with one well-defined reduction wave at -0.83 V (vs. Ag/AgCl, KCl, 3.5 mol dm(-3)). A linear response was observed for three concentration ranges 1-5, 5-15 and 15-30 mg dm(-3), with an achieved limit of detection of 0.042 mg dm(-3). The precision was determined as a function of repeatability and reproducibility, which showed relative standard deviation values not higher than 3.18%. Various interfering substances did not interfere with metribuzin determination.... The proposed method was successfully applied to tap and river water samples. The recovery values obtained for spiked river water samples were in good statistical agreement with those obtained by the LC-MS/MS method. Accordingly, the proposed chronopotentiometric methodology can be conveniently applied in the quality control of environmental water samples as a simple, sensitive, reliable and low cost method.
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Analytical Methods, 2016, 8, 12, 2698-2705Publisher:
- Royal Soc Chemistry, Cambridge
Funding / projects:
DOI: 10.1039/c5ay03243a
ISSN: 1759-9660
WoS: 000372758000019
Scopus: 2-s2.0-84962552609
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FiVeRTY - JOUR AU - Stojanović, Zorica AU - Đurović, Ana AU - Kravić, Snežana AU - Grahovac, Nada AU - Suturović, Zvonimir AU - Bursić, Vojislava AU - Vuković, Gorica AU - Brezo, Tanja PY - 2016 UR - http://fiver.ifvcns.rs/handle/123456789/1553 AB - This paper describes an electroanalytical method for the determination of metribuzin using a thin film mercury electrode by chronopotentiometry. Research included optimization of the most important parameters of chronopotentiometric analysis and the best responses were achieved in Britton-Robinson buffer at pH 5.0, using an initial potential of -0.21 V, ending potential of -1.1 V, and reduction current in the range from -4 mu A to -15 mA. Under these conditions, metribuzin was reduced in an irreversible electrode reaction process with one well-defined reduction wave at -0.83 V (vs. Ag/AgCl, KCl, 3.5 mol dm(-3)). A linear response was observed for three concentration ranges 1-5, 5-15 and 15-30 mg dm(-3), with an achieved limit of detection of 0.042 mg dm(-3). The precision was determined as a function of repeatability and reproducibility, which showed relative standard deviation values not higher than 3.18%. Various interfering substances did not interfere with metribuzin determination. The proposed method was successfully applied to tap and river water samples. The recovery values obtained for spiked river water samples were in good statistical agreement with those obtained by the LC-MS/MS method. Accordingly, the proposed chronopotentiometric methodology can be conveniently applied in the quality control of environmental water samples as a simple, sensitive, reliable and low cost method. PB - Royal Soc Chemistry, Cambridge T2 - Analytical Methods T1 - A simple and rapid electrochemical sensing method for metribuzin determination in tap and river water samples EP - 2705 IS - 12 SP - 2698 VL - 8 DO - 10.1039/c5ay03243a ER -
@article{ author = "Stojanović, Zorica and Đurović, Ana and Kravić, Snežana and Grahovac, Nada and Suturović, Zvonimir and Bursić, Vojislava and Vuković, Gorica and Brezo, Tanja", year = "2016", abstract = "This paper describes an electroanalytical method for the determination of metribuzin using a thin film mercury electrode by chronopotentiometry. Research included optimization of the most important parameters of chronopotentiometric analysis and the best responses were achieved in Britton-Robinson buffer at pH 5.0, using an initial potential of -0.21 V, ending potential of -1.1 V, and reduction current in the range from -4 mu A to -15 mA. Under these conditions, metribuzin was reduced in an irreversible electrode reaction process with one well-defined reduction wave at -0.83 V (vs. Ag/AgCl, KCl, 3.5 mol dm(-3)). A linear response was observed for three concentration ranges 1-5, 5-15 and 15-30 mg dm(-3), with an achieved limit of detection of 0.042 mg dm(-3). The precision was determined as a function of repeatability and reproducibility, which showed relative standard deviation values not higher than 3.18%. Various interfering substances did not interfere with metribuzin determination. The proposed method was successfully applied to tap and river water samples. The recovery values obtained for spiked river water samples were in good statistical agreement with those obtained by the LC-MS/MS method. Accordingly, the proposed chronopotentiometric methodology can be conveniently applied in the quality control of environmental water samples as a simple, sensitive, reliable and low cost method.", publisher = "Royal Soc Chemistry, Cambridge", journal = "Analytical Methods", title = "A simple and rapid electrochemical sensing method for metribuzin determination in tap and river water samples", pages = "2705-2698", number = "12", volume = "8", doi = "10.1039/c5ay03243a" }
Stojanović, Z., Đurović, A., Kravić, S., Grahovac, N., Suturović, Z., Bursić, V., Vuković, G.,& Brezo, T.. (2016). A simple and rapid electrochemical sensing method for metribuzin determination in tap and river water samples. in Analytical Methods Royal Soc Chemistry, Cambridge., 8(12), 2698-2705. https://doi.org/10.1039/c5ay03243a
Stojanović Z, Đurović A, Kravić S, Grahovac N, Suturović Z, Bursić V, Vuković G, Brezo T. A simple and rapid electrochemical sensing method for metribuzin determination in tap and river water samples. in Analytical Methods. 2016;8(12):2698-2705. doi:10.1039/c5ay03243a .
Stojanović, Zorica, Đurović, Ana, Kravić, Snežana, Grahovac, Nada, Suturović, Zvonimir, Bursić, Vojislava, Vuković, Gorica, Brezo, Tanja, "A simple and rapid electrochemical sensing method for metribuzin determination in tap and river water samples" in Analytical Methods, 8, no. 12 (2016):2698-2705, https://doi.org/10.1039/c5ay03243a . .