Monitoring atrazina i njegovih metabolita u podzemnim vodama Republike Srbije
Monitoring of atrazine and its metabolites in groundwaters of the Republic of Serbia
Authors
Lazić, SanjaŠunjka, Dragana
Pucarević, Mira
Grahovac, Nada
Vuković, Slavica
Inđić, Dušanka
Jakšić, Snežana
Article (Published version)
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Ekspanzija u primeni herbicida na bazi atrazina u Republici Srbiji poslednjih decenija dovela je do nagomilavanja ostataka atrazina i njegovih degradacionih produkata u životnoj sredini, čime su naročito ugrožene podzemne vode. Radi provere prisustva atrazina i njegovih metabolita deetil-atrazina (DEA) i deizopropil-atrazina (DIA) u podzemnim vodama sproveden je monitoring program u periodu 2007−2009. godine na područjima pod intenzivnom poljoprivrednom proizvodnjom na teritoriji Republike Srbije. Podzemna voda prve izdani uzorkovana je na 327 lokaliteta, ukupno je prikupljeno 1408 uzoraka. Ekstrakcija analita iz vode izvedena je metanolom uz primenu C18-ENVI diska (47 mm), dok je nivo rezidua određen primenom gasne hromatografije sa masenim spektrometrom (GC/MS). Analizom je utvrđeno prisustvo atrazina, DEA i DIA iznad 0,1 µg/dm³ u podzemnim vodama većine lokaliteta obuhvaćenih ispitivanjem. Najveće vrednosti ispitivanih analita utvrđene su na lokalitetima sa intenzivnom proizvodnjom ...kukuruza, kao i na površinama pod voćnjacima i vinogradima, gde je atrazin primenjivan u velikim količinama.
The intensive use of atrazine herbicides in the Republic of Serbia during recent decades has led to the accumulation of residues of atrazine and its metabolites in the environment, which endangers groundwater. With the objective to check the presence of atrazine and its metabolites deethylatrazine (DEA) and deisopropylatrazine (DIA) in the groundwater, the monitoring programme was carried out over the period from 2007 to 2009 in the localities where the atrazine-based herbicides were intensively applied for a number of years. Samples were taken from 327 localities, in total there were 1408 samples of groundwater of the first welling-up collected. The atrazine and its metabolites were extracted with methanol by means of ENVI-C18 (47mm) disc, and the residue level of the studied compounds was analyzed with gas chromatography–mass spectrometry (GC–MS). In the most of groundwater samples collected from agricultural regions, the average value of all tested analytes was above 0.1 μg/dm3. The... highest values of atrazine and its metabolites were in the localities that are known for intensive maize production and in the areas of this region under orchards and vineyards, where atrazine was used in large quantities. The average content values of this active substance in the analyzed samples are the result of intensive and long-term usage of this group of herbicides, as well as the high level of groundwater in this
region.
Keywords:
atrazin / DEA / DIA / podzemna voda / monitoring / groundwater / atrazine / metabolites / metaboliti / Srbija / SerbiaSource:
Hemijska industrija, 2012, 67, 3, 513-523Publisher:
- Association of the Chemical Engineers of Serbia
Funding / projects:
- Improving remediation technologies and developing methods for the risk assessment of contaminated sites (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43005)
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Institution/Community
FiVeRTY - JOUR AU - Lazić, Sanja AU - Šunjka, Dragana AU - Pucarević, Mira AU - Grahovac, Nada AU - Vuković, Slavica AU - Inđić, Dušanka AU - Jakšić, Snežana PY - 2012 UR - http://fiver.ifvcns.rs/handle/123456789/3295 AB - Ekspanzija u primeni herbicida na bazi atrazina u Republici Srbiji poslednjih decenija dovela je do nagomilavanja ostataka atrazina i njegovih degradacionih produkata u životnoj sredini, čime su naročito ugrožene podzemne vode. Radi provere prisustva atrazina i njegovih metabolita deetil-atrazina (DEA) i deizopropil-atrazina (DIA) u podzemnim vodama sproveden je monitoring program u periodu 2007−2009. godine na područjima pod intenzivnom poljoprivrednom proizvodnjom na teritoriji Republike Srbije. Podzemna voda prve izdani uzorkovana je na 327 lokaliteta, ukupno je prikupljeno 1408 uzoraka. Ekstrakcija analita iz vode izvedena je metanolom uz primenu C18-ENVI diska (47 mm), dok je nivo rezidua određen primenom gasne hromatografije sa masenim spektrometrom (GC/MS). Analizom je utvrđeno prisustvo atrazina, DEA i DIA iznad 0,1 µg/dm³ u podzemnim vodama većine lokaliteta obuhvaćenih ispitivanjem. Najveće vrednosti ispitivanih analita utvrđene su na lokalitetima sa intenzivnom proizvodnjom kukuruza, kao i na površinama pod voćnjacima i vinogradima, gde je atrazin primenjivan u velikim količinama. AB - The intensive use of atrazine herbicides in the Republic of Serbia during recent decades has led to the accumulation of residues of atrazine and its metabolites in the environment, which endangers groundwater. With the objective to check the presence of atrazine and its metabolites deethylatrazine (DEA) and deisopropylatrazine (DIA) in the groundwater, the monitoring programme was carried out over the period from 2007 to 2009 in the localities where the atrazine-based herbicides were intensively applied for a number of years. Samples were taken from 327 localities, in total there were 1408 samples of groundwater of the first welling-up collected. The atrazine and its metabolites were extracted with methanol by means of ENVI-C18 (47mm) disc, and the residue level of the studied compounds was analyzed with gas chromatography–mass spectrometry (GC–MS). In the most of groundwater samples collected from agricultural regions, the average value of all tested analytes was above 0.1 μg/dm3. The highest values of atrazine and its metabolites were in the localities that are known for intensive maize production and in the areas of this region under orchards and vineyards, where atrazine was used in large quantities. The average content values of this active substance in the analyzed samples are the result of intensive and long-term usage of this group of herbicides, as well as the high level of groundwater in this region. PB - Association of the Chemical Engineers of Serbia T2 - Hemijska industrija T1 - Monitoring atrazina i njegovih metabolita u podzemnim vodama Republike Srbije T1 - Monitoring of atrazine and its metabolites in groundwaters of the Republic of Serbia EP - 523 IS - 3 SP - 513 VL - 67 DO - 10.2298/HEMIND120508094L ER -
@article{ author = "Lazić, Sanja and Šunjka, Dragana and Pucarević, Mira and Grahovac, Nada and Vuković, Slavica and Inđić, Dušanka and Jakšić, Snežana", year = "2012", abstract = "Ekspanzija u primeni herbicida na bazi atrazina u Republici Srbiji poslednjih decenija dovela je do nagomilavanja ostataka atrazina i njegovih degradacionih produkata u životnoj sredini, čime su naročito ugrožene podzemne vode. Radi provere prisustva atrazina i njegovih metabolita deetil-atrazina (DEA) i deizopropil-atrazina (DIA) u podzemnim vodama sproveden je monitoring program u periodu 2007−2009. godine na područjima pod intenzivnom poljoprivrednom proizvodnjom na teritoriji Republike Srbije. Podzemna voda prve izdani uzorkovana je na 327 lokaliteta, ukupno je prikupljeno 1408 uzoraka. Ekstrakcija analita iz vode izvedena je metanolom uz primenu C18-ENVI diska (47 mm), dok je nivo rezidua određen primenom gasne hromatografije sa masenim spektrometrom (GC/MS). Analizom je utvrđeno prisustvo atrazina, DEA i DIA iznad 0,1 µg/dm³ u podzemnim vodama većine lokaliteta obuhvaćenih ispitivanjem. Najveće vrednosti ispitivanih analita utvrđene su na lokalitetima sa intenzivnom proizvodnjom kukuruza, kao i na površinama pod voćnjacima i vinogradima, gde je atrazin primenjivan u velikim količinama., The intensive use of atrazine herbicides in the Republic of Serbia during recent decades has led to the accumulation of residues of atrazine and its metabolites in the environment, which endangers groundwater. With the objective to check the presence of atrazine and its metabolites deethylatrazine (DEA) and deisopropylatrazine (DIA) in the groundwater, the monitoring programme was carried out over the period from 2007 to 2009 in the localities where the atrazine-based herbicides were intensively applied for a number of years. Samples were taken from 327 localities, in total there were 1408 samples of groundwater of the first welling-up collected. The atrazine and its metabolites were extracted with methanol by means of ENVI-C18 (47mm) disc, and the residue level of the studied compounds was analyzed with gas chromatography–mass spectrometry (GC–MS). In the most of groundwater samples collected from agricultural regions, the average value of all tested analytes was above 0.1 μg/dm3. The highest values of atrazine and its metabolites were in the localities that are known for intensive maize production and in the areas of this region under orchards and vineyards, where atrazine was used in large quantities. The average content values of this active substance in the analyzed samples are the result of intensive and long-term usage of this group of herbicides, as well as the high level of groundwater in this region.", publisher = "Association of the Chemical Engineers of Serbia", journal = "Hemijska industrija", title = "Monitoring atrazina i njegovih metabolita u podzemnim vodama Republike Srbije, Monitoring of atrazine and its metabolites in groundwaters of the Republic of Serbia", pages = "523-513", number = "3", volume = "67", doi = "10.2298/HEMIND120508094L" }
Lazić, S., Šunjka, D., Pucarević, M., Grahovac, N., Vuković, S., Inđić, D.,& Jakšić, S.. (2012). Monitoring atrazina i njegovih metabolita u podzemnim vodama Republike Srbije. in Hemijska industrija Association of the Chemical Engineers of Serbia., 67(3), 513-523. https://doi.org/10.2298/HEMIND120508094L
Lazić S, Šunjka D, Pucarević M, Grahovac N, Vuković S, Inđić D, Jakšić S. Monitoring atrazina i njegovih metabolita u podzemnim vodama Republike Srbije. in Hemijska industrija. 2012;67(3):513-523. doi:10.2298/HEMIND120508094L .
Lazić, Sanja, Šunjka, Dragana, Pucarević, Mira, Grahovac, Nada, Vuković, Slavica, Inđić, Dušanka, Jakšić, Snežana, "Monitoring atrazina i njegovih metabolita u podzemnim vodama Republike Srbije" in Hemijska industrija, 67, no. 3 (2012):513-523, https://doi.org/10.2298/HEMIND120508094L . .