The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil
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2020
Authors
Đorđević, Biljana S.Troter, Dragan Z.
Todorović, Zoran B.
Đalović, Ivica
Stanojević, Ljiljana P.
Mitrović, Petar
Veljković, Vlada B.
Article (Published version)
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This study reports the yields, physicochemical properties, fatty acid compositions, and antioxidant activities of black mustard (Brassica nigraL.) seed oils extracted by cold pressing and the solvent extraction using different solvents (n-hexane, trichloroethylene, and a mixture of trichloroethylene and the triethanolamine:glycerol deep eutectic solvent (TEOA:G DES) with no or after pretreatment with the TEOA:G DES. Density (0.9791 +/- 0.0003-0.9851 +/- 0.0003 g/cm(3)), viscosity (121.15 +/- 1.62-123.32 +/- 0.10 mPas), boiling point (179-185 +/- 1 degrees C), refractive index (1.4692 +/- 0.0006-1.4758 +/- 0.0011), acid (2.08 +/- 0.19-3.22 +/- 0.15 mg KOH/g), iodine (99.2 +/- 1.6-105.4 +/- 1.5 g I-2/100 g), peroxide (1.68 +/- 0.01-1.82 +/- 0.03 mmol O-2/kg), and saponification values (165.1 +/- 2.7-169.4 +/- 2.3 mg KOH/g), fatty acid composition and antioxidant activity of the extracted oil were determined in order to evaluate its potential use as a foodstuff, a pharmaceutical or a feed...stock for biodiesel production. Although the maceration of black mustard seeds with sole trichloroethylene yielded the highest oil yield of 31.10 +/- 0.42 g/100 g, it required almost twice the volume of trichloroethylene compared to the volume applied in the macerations after the pre-treatment with the TEOA:G DES and with the mixture of trichloroethylene/TEOA:G DES. The oil extracted by the extraction in the presence of TEOA:G DES has similar physicochemical properties but better antioxidant activity than the oil extracted by cold pressing.
Keywords:
Black mustard seed oil / Extraction / Brassica nigra / Deep eutectic solvent / Antioxidant activitySource:
Journal of Food Measurement & Characterization, 2020, 14, 5, 2570-2577Publisher:
- Springer, New York
Funding / projects:
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- Serbian Academy of Sciences and Arts [F-78]
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200133 (Univeristy of Niš, Faculty of Technology, Leskovac) (RS-MESTD-inst-2020-200133)
DOI: 10.1007/s11694-020-00503-3
ISSN: 2193-4126
WoS: 000539345700001
Scopus: 2-s2.0-85086119104
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FiVeRTY - JOUR AU - Đorđević, Biljana S. AU - Troter, Dragan Z. AU - Todorović, Zoran B. AU - Đalović, Ivica AU - Stanojević, Ljiljana P. AU - Mitrović, Petar AU - Veljković, Vlada B. PY - 2020 UR - http://fiver.ifvcns.rs/handle/123456789/1971 AB - This study reports the yields, physicochemical properties, fatty acid compositions, and antioxidant activities of black mustard (Brassica nigraL.) seed oils extracted by cold pressing and the solvent extraction using different solvents (n-hexane, trichloroethylene, and a mixture of trichloroethylene and the triethanolamine:glycerol deep eutectic solvent (TEOA:G DES) with no or after pretreatment with the TEOA:G DES. Density (0.9791 +/- 0.0003-0.9851 +/- 0.0003 g/cm(3)), viscosity (121.15 +/- 1.62-123.32 +/- 0.10 mPas), boiling point (179-185 +/- 1 degrees C), refractive index (1.4692 +/- 0.0006-1.4758 +/- 0.0011), acid (2.08 +/- 0.19-3.22 +/- 0.15 mg KOH/g), iodine (99.2 +/- 1.6-105.4 +/- 1.5 g I-2/100 g), peroxide (1.68 +/- 0.01-1.82 +/- 0.03 mmol O-2/kg), and saponification values (165.1 +/- 2.7-169.4 +/- 2.3 mg KOH/g), fatty acid composition and antioxidant activity of the extracted oil were determined in order to evaluate its potential use as a foodstuff, a pharmaceutical or a feedstock for biodiesel production. Although the maceration of black mustard seeds with sole trichloroethylene yielded the highest oil yield of 31.10 +/- 0.42 g/100 g, it required almost twice the volume of trichloroethylene compared to the volume applied in the macerations after the pre-treatment with the TEOA:G DES and with the mixture of trichloroethylene/TEOA:G DES. The oil extracted by the extraction in the presence of TEOA:G DES has similar physicochemical properties but better antioxidant activity than the oil extracted by cold pressing. PB - Springer, New York T2 - Journal of Food Measurement & Characterization T1 - The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil EP - 2577 IS - 5 SP - 2570 VL - 14 DO - 10.1007/s11694-020-00503-3 ER -
@article{ author = "Đorđević, Biljana S. and Troter, Dragan Z. and Todorović, Zoran B. and Đalović, Ivica and Stanojević, Ljiljana P. and Mitrović, Petar and Veljković, Vlada B.", year = "2020", abstract = "This study reports the yields, physicochemical properties, fatty acid compositions, and antioxidant activities of black mustard (Brassica nigraL.) seed oils extracted by cold pressing and the solvent extraction using different solvents (n-hexane, trichloroethylene, and a mixture of trichloroethylene and the triethanolamine:glycerol deep eutectic solvent (TEOA:G DES) with no or after pretreatment with the TEOA:G DES. Density (0.9791 +/- 0.0003-0.9851 +/- 0.0003 g/cm(3)), viscosity (121.15 +/- 1.62-123.32 +/- 0.10 mPas), boiling point (179-185 +/- 1 degrees C), refractive index (1.4692 +/- 0.0006-1.4758 +/- 0.0011), acid (2.08 +/- 0.19-3.22 +/- 0.15 mg KOH/g), iodine (99.2 +/- 1.6-105.4 +/- 1.5 g I-2/100 g), peroxide (1.68 +/- 0.01-1.82 +/- 0.03 mmol O-2/kg), and saponification values (165.1 +/- 2.7-169.4 +/- 2.3 mg KOH/g), fatty acid composition and antioxidant activity of the extracted oil were determined in order to evaluate its potential use as a foodstuff, a pharmaceutical or a feedstock for biodiesel production. Although the maceration of black mustard seeds with sole trichloroethylene yielded the highest oil yield of 31.10 +/- 0.42 g/100 g, it required almost twice the volume of trichloroethylene compared to the volume applied in the macerations after the pre-treatment with the TEOA:G DES and with the mixture of trichloroethylene/TEOA:G DES. The oil extracted by the extraction in the presence of TEOA:G DES has similar physicochemical properties but better antioxidant activity than the oil extracted by cold pressing.", publisher = "Springer, New York", journal = "Journal of Food Measurement & Characterization", title = "The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil", pages = "2577-2570", number = "5", volume = "14", doi = "10.1007/s11694-020-00503-3" }
Đorđević, B. S., Troter, D. Z., Todorović, Z. B., Đalović, I., Stanojević, L. P., Mitrović, P.,& Veljković, V. B.. (2020). The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil. in Journal of Food Measurement & Characterization Springer, New York., 14(5), 2570-2577. https://doi.org/10.1007/s11694-020-00503-3
Đorđević BS, Troter DZ, Todorović ZB, Đalović I, Stanojević LP, Mitrović P, Veljković VB. The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil. in Journal of Food Measurement & Characterization. 2020;14(5):2570-2577. doi:10.1007/s11694-020-00503-3 .
Đorđević, Biljana S., Troter, Dragan Z., Todorović, Zoran B., Đalović, Ivica, Stanojević, Ljiljana P., Mitrović, Petar, Veljković, Vlada B., "The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil" in Journal of Food Measurement & Characterization, 14, no. 5 (2020):2570-2577, https://doi.org/10.1007/s11694-020-00503-3 . .