LC-MS/MS Determination of Tropane Alkaloids in Maize Crop
Само за регистроване кориснике
2018
Аутори
Vuković, GoricaBursić, Vojislava
Stojanović, Tijana
Petrović, Aleksandra
Gvozdenac, Sonja
Starović, Mira
Kuzmanović, Slobodan
Aleksić, Goran
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The undemanding LC-MS/MS method was developed for the synchronized analysis of atropine and scopolamine in maize crop. The dSPE was carried out with 1% acetic acid in acetonitrile/water and a mixture of magnesium sulphate, sodium chloride and sodium citrate. The analytes were separated on a Zorbax XDB C18 column using methanol/water as the mobile phase in gradient mode. The detection was done using a tandem masss spectrometry (MS/MS) in the positive ESI. The tropane alkaloids exhibited excellent linearity in the range of 2-20 µg/kg with the LOQ of 5 µg/kg for maize. The extraction recoveries of atropine and scopolamine were 65.7 and 85.5% with the intraday RSDr 10.25 and 4.29%, respectively. The validated method was appled to real maze samples. One sample contained 18.8 µg/kg of atropine and 6.3 µg/kg of scopolamine.
Кључне речи:
atropine / scopolamine / maizeИзвор:
Savremena poljoprivreda, 2018, 67, 3-4, 221-226Издавач:
- Novi Sad : Univerzitet u Novom Sadu - Poljoprivredni fakultet
- Novi Sad : Naučni institut za ratarstvo i povrtarstvo
Финансирање / пројекти:
- Разрада интегрисаног управљања и примене савремених принципа сузбијања штетних организама у заштити биља (RS-MESTD-Technological Development (TD or TR)-31018)
Колекције
Институција/група
FiVeRTY - JOUR AU - Vuković, Gorica AU - Bursić, Vojislava AU - Stojanović, Tijana AU - Petrović, Aleksandra AU - Gvozdenac, Sonja AU - Starović, Mira AU - Kuzmanović, Slobodan AU - Aleksić, Goran PY - 2018 UR - http://fiver.ifvcns.rs/handle/123456789/1831 AB - The undemanding LC-MS/MS method was developed for the synchronized analysis of atropine and scopolamine in maize crop. The dSPE was carried out with 1% acetic acid in acetonitrile/water and a mixture of magnesium sulphate, sodium chloride and sodium citrate. The analytes were separated on a Zorbax XDB C18 column using methanol/water as the mobile phase in gradient mode. The detection was done using a tandem masss spectrometry (MS/MS) in the positive ESI. The tropane alkaloids exhibited excellent linearity in the range of 2-20 µg/kg with the LOQ of 5 µg/kg for maize. The extraction recoveries of atropine and scopolamine were 65.7 and 85.5% with the intraday RSDr 10.25 and 4.29%, respectively. The validated method was appled to real maze samples. One sample contained 18.8 µg/kg of atropine and 6.3 µg/kg of scopolamine. PB - Novi Sad : Univerzitet u Novom Sadu - Poljoprivredni fakultet PB - Novi Sad : Naučni institut za ratarstvo i povrtarstvo T2 - Savremena poljoprivreda T1 - LC-MS/MS Determination of Tropane Alkaloids in Maize Crop EP - 226 IS - 3-4 SP - 221 VL - 67 DO - 10.1515/contagri-2018-0032 ER -
@article{ author = "Vuković, Gorica and Bursić, Vojislava and Stojanović, Tijana and Petrović, Aleksandra and Gvozdenac, Sonja and Starović, Mira and Kuzmanović, Slobodan and Aleksić, Goran", year = "2018", abstract = "The undemanding LC-MS/MS method was developed for the synchronized analysis of atropine and scopolamine in maize crop. The dSPE was carried out with 1% acetic acid in acetonitrile/water and a mixture of magnesium sulphate, sodium chloride and sodium citrate. The analytes were separated on a Zorbax XDB C18 column using methanol/water as the mobile phase in gradient mode. The detection was done using a tandem masss spectrometry (MS/MS) in the positive ESI. The tropane alkaloids exhibited excellent linearity in the range of 2-20 µg/kg with the LOQ of 5 µg/kg for maize. The extraction recoveries of atropine and scopolamine were 65.7 and 85.5% with the intraday RSDr 10.25 and 4.29%, respectively. The validated method was appled to real maze samples. One sample contained 18.8 µg/kg of atropine and 6.3 µg/kg of scopolamine.", publisher = "Novi Sad : Univerzitet u Novom Sadu - Poljoprivredni fakultet, Novi Sad : Naučni institut za ratarstvo i povrtarstvo", journal = "Savremena poljoprivreda", title = "LC-MS/MS Determination of Tropane Alkaloids in Maize Crop", pages = "226-221", number = "3-4", volume = "67", doi = "10.1515/contagri-2018-0032" }
Vuković, G., Bursić, V., Stojanović, T., Petrović, A., Gvozdenac, S., Starović, M., Kuzmanović, S.,& Aleksić, G.. (2018). LC-MS/MS Determination of Tropane Alkaloids in Maize Crop. in Savremena poljoprivreda Novi Sad : Univerzitet u Novom Sadu - Poljoprivredni fakultet., 67(3-4), 221-226. https://doi.org/10.1515/contagri-2018-0032
Vuković G, Bursić V, Stojanović T, Petrović A, Gvozdenac S, Starović M, Kuzmanović S, Aleksić G. LC-MS/MS Determination of Tropane Alkaloids in Maize Crop. in Savremena poljoprivreda. 2018;67(3-4):221-226. doi:10.1515/contagri-2018-0032 .
Vuković, Gorica, Bursić, Vojislava, Stojanović, Tijana, Petrović, Aleksandra, Gvozdenac, Sonja, Starović, Mira, Kuzmanović, Slobodan, Aleksić, Goran, "LC-MS/MS Determination of Tropane Alkaloids in Maize Crop" in Savremena poljoprivreda, 67, no. 3-4 (2018):221-226, https://doi.org/10.1515/contagri-2018-0032 . .