Raman spectroscopy coupled with chemometric modeling approaches for authentication of different paprika varieties at physiological maturity
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Five Balkan paprika varieties at physiological maturity were investigated by means of Raman spectroscopy in order to discriminate the differences which stemmed from their genetic variability since the plants were grown under the same experimental conditions. The spectra were obtained using the 532 nm wavelength. In an effort to find the best classification power, several pre-processing methods were applied: 1) baseline correction, unit vector normalization; 2) baseline correction, unit vector normalization and first Savitzky-Golay derivative; 3) baseline correction, unit vector normalization and second Savitzky-Golay derivative; 4) baseline correction, unit
vector normalization and third Savitzky-Golay derivative. All of the pre-processing methods were followed by
making PCA-LDA (Principal Component Analysis-Linear Discriminant Analysis), QDA (Quadratic Discriminant
Analysis), and PLS-DA (Partial Least Square - Discriminant Analysis) classification models. QDA showed the best dis...crimination power (83.87–100% and 89.47–100% for the training and the test data, respectively), then PCA-LDA (0.00–100 and 0.00–100% for the training and the test data, respectively) and PLS-DA (19.35–100% and 0.00–100.00% for the training and the test data, respectively). The results pointed out the applicability of
chemometric modeling associated with Raman spectroscopy in the assessment of nutritionally similar samples,
such as the studied red paprika varieties.
Кључне речи:
Capsicum annuum / carotenoids / Raman spectroscopy / multivariate classification / paprika / varieties / genetic variability / chemometric modeling / red paprikaИзвор:
LWT Food Science and Technology, 2022, 162, 113402-Издавач:
- Elsevier
Финансирање / пројекти:
- R-SPECT - Novel Raman chemometrics-based approach in food quality assessment: Carotenoids as model nutrients for application to functional products (RS-ScienceFundRS-Ideje-7750160)
DOI: 10.1016/j.lwt.2022.113402
ISSN: 0023-6438
WoS: 00079579050000
Scopus: 2-s2.0-85128905011
Колекције
Институција/група
FiVeRTY - JOUR AU - Kolašinac, Stefan AU - Pećinar, Ilinka AU - Danojević, Dario AU - Dajić Stevanović, Zora PY - 2022 UR - http://fiver.ifvcns.rs/handle/123456789/2651 AB - Five Balkan paprika varieties at physiological maturity were investigated by means of Raman spectroscopy in order to discriminate the differences which stemmed from their genetic variability since the plants were grown under the same experimental conditions. The spectra were obtained using the 532 nm wavelength. In an effort to find the best classification power, several pre-processing methods were applied: 1) baseline correction, unit vector normalization; 2) baseline correction, unit vector normalization and first Savitzky-Golay derivative; 3) baseline correction, unit vector normalization and second Savitzky-Golay derivative; 4) baseline correction, unit vector normalization and third Savitzky-Golay derivative. All of the pre-processing methods were followed by making PCA-LDA (Principal Component Analysis-Linear Discriminant Analysis), QDA (Quadratic Discriminant Analysis), and PLS-DA (Partial Least Square - Discriminant Analysis) classification models. QDA showed the best discrimination power (83.87–100% and 89.47–100% for the training and the test data, respectively), then PCA-LDA (0.00–100 and 0.00–100% for the training and the test data, respectively) and PLS-DA (19.35–100% and 0.00–100.00% for the training and the test data, respectively). The results pointed out the applicability of chemometric modeling associated with Raman spectroscopy in the assessment of nutritionally similar samples, such as the studied red paprika varieties. PB - Elsevier T2 - LWT Food Science and Technology T1 - Raman spectroscopy coupled with chemometric modeling approaches for authentication of different paprika varieties at physiological maturity SP - 113402 VL - 162 DO - 10.1016/j.lwt.2022.113402 ER -
@article{ author = "Kolašinac, Stefan and Pećinar, Ilinka and Danojević, Dario and Dajić Stevanović, Zora", year = "2022", abstract = "Five Balkan paprika varieties at physiological maturity were investigated by means of Raman spectroscopy in order to discriminate the differences which stemmed from their genetic variability since the plants were grown under the same experimental conditions. The spectra were obtained using the 532 nm wavelength. In an effort to find the best classification power, several pre-processing methods were applied: 1) baseline correction, unit vector normalization; 2) baseline correction, unit vector normalization and first Savitzky-Golay derivative; 3) baseline correction, unit vector normalization and second Savitzky-Golay derivative; 4) baseline correction, unit vector normalization and third Savitzky-Golay derivative. All of the pre-processing methods were followed by making PCA-LDA (Principal Component Analysis-Linear Discriminant Analysis), QDA (Quadratic Discriminant Analysis), and PLS-DA (Partial Least Square - Discriminant Analysis) classification models. QDA showed the best discrimination power (83.87–100% and 89.47–100% for the training and the test data, respectively), then PCA-LDA (0.00–100 and 0.00–100% for the training and the test data, respectively) and PLS-DA (19.35–100% and 0.00–100.00% for the training and the test data, respectively). The results pointed out the applicability of chemometric modeling associated with Raman spectroscopy in the assessment of nutritionally similar samples, such as the studied red paprika varieties.", publisher = "Elsevier", journal = "LWT Food Science and Technology", title = "Raman spectroscopy coupled with chemometric modeling approaches for authentication of different paprika varieties at physiological maturity", pages = "113402", volume = "162", doi = "10.1016/j.lwt.2022.113402" }
Kolašinac, S., Pećinar, I., Danojević, D.,& Dajić Stevanović, Z.. (2022). Raman spectroscopy coupled with chemometric modeling approaches for authentication of different paprika varieties at physiological maturity. in LWT Food Science and Technology Elsevier., 162, 113402. https://doi.org/10.1016/j.lwt.2022.113402
Kolašinac S, Pećinar I, Danojević D, Dajić Stevanović Z. Raman spectroscopy coupled with chemometric modeling approaches for authentication of different paprika varieties at physiological maturity. in LWT Food Science and Technology. 2022;162:113402. doi:10.1016/j.lwt.2022.113402 .
Kolašinac, Stefan, Pećinar, Ilinka, Danojević, Dario, Dajić Stevanović, Zora, "Raman spectroscopy coupled with chemometric modeling approaches for authentication of different paprika varieties at physiological maturity" in LWT Food Science and Technology, 162 (2022):113402, https://doi.org/10.1016/j.lwt.2022.113402 . .