Serbian Academy of Sciences and Arts [F-78]

Link to this page

Serbian Academy of Sciences and Arts [F-78]

Authors

Publications

Extraction of phenolic compounds from black mustard (Brassica nigra L.) seed by deep eutectic solvents

Đorđević, Biljana S.; Todorović, Zoran B.; Troter, Dragan Z.; Stanojević, Ljiljana P.; Stojanović, Gordana S.; Đalović, Ivica; Mitrović, Petar; Veljković, Vlada B.

(Springer, New York, 2021)

TY  - JOUR
AU  - Đorđević, Biljana S.
AU  - Todorović, Zoran B.
AU  - Troter, Dragan Z.
AU  - Stanojević, Ljiljana P.
AU  - Stojanović, Gordana S.
AU  - Đalović, Ivica
AU  - Mitrović, Petar
AU  - Veljković, Vlada B.
PY  - 2021
UR  - http://fiver.ifvcns.rs/handle/123456789/2086
AB  - This study reports for the first time the total extractive matter yield, total phenolics and total flavonoids content (TPC and TFC, respectively), chemical composition, and ability to scavenging 2,2-diphenyl-1-picrylhydrazyl (DPPH) radicals of the black mustard seed (BMS) extracts obtained by deep eutectic solvents (DESs). The following DESs: triethanolamine:glycerol (TEOA:G), triethanolamine:propylene glycol (TEOA:PEG), and choline chloride:urea (ChCl:U), as well as their mixtures with water and ethanol at a ratio of 1:4 (v/v), were used. Their extraction efficiencies were compared with the efficiency of ethanol that is most frequently used to extract phenolic compounds from BMS. The TPC and TFC of the obtained extracts were in the ranges of 19.9 +/- 0.1 to 32.2 +/- 0.2 mg gallic acid equivalents/g and 3.9 +/- 0.1 to 7.4 +/- 0.3 mg quercetin equivalents/g, respectively. The BMS extracts obtained with the pure ChCl:U and the mixtures of ChCl:U or TEOA:G with ethanol showed the best antioxidant activity (IC50 = 100 mg/mL). The obtained extracts contained syringic acid, ellagic acid, gallic acid, caffeic acid, caftaric acid, rutin, kaempferol, apigenin, taxifolin, hyperoside, and vitexin.
PB  - Springer, New York
T2  - Journal of Food Measurement & Characterization
T1  - Extraction of phenolic compounds from black mustard (Brassica nigra L.) seed by deep eutectic solvents
EP  - 1938
IS  - 2
SP  - 1931
VL  - 15
DO  - 10.1007/s11694-020-00772-y
ER  - 
@article{
author = "Đorđević, Biljana S. and Todorović, Zoran B. and Troter, Dragan Z. and Stanojević, Ljiljana P. and Stojanović, Gordana S. and Đalović, Ivica and Mitrović, Petar and Veljković, Vlada B.",
year = "2021",
abstract = "This study reports for the first time the total extractive matter yield, total phenolics and total flavonoids content (TPC and TFC, respectively), chemical composition, and ability to scavenging 2,2-diphenyl-1-picrylhydrazyl (DPPH) radicals of the black mustard seed (BMS) extracts obtained by deep eutectic solvents (DESs). The following DESs: triethanolamine:glycerol (TEOA:G), triethanolamine:propylene glycol (TEOA:PEG), and choline chloride:urea (ChCl:U), as well as their mixtures with water and ethanol at a ratio of 1:4 (v/v), were used. Their extraction efficiencies were compared with the efficiency of ethanol that is most frequently used to extract phenolic compounds from BMS. The TPC and TFC of the obtained extracts were in the ranges of 19.9 +/- 0.1 to 32.2 +/- 0.2 mg gallic acid equivalents/g and 3.9 +/- 0.1 to 7.4 +/- 0.3 mg quercetin equivalents/g, respectively. The BMS extracts obtained with the pure ChCl:U and the mixtures of ChCl:U or TEOA:G with ethanol showed the best antioxidant activity (IC50 = 100 mg/mL). The obtained extracts contained syringic acid, ellagic acid, gallic acid, caffeic acid, caftaric acid, rutin, kaempferol, apigenin, taxifolin, hyperoside, and vitexin.",
publisher = "Springer, New York",
journal = "Journal of Food Measurement & Characterization",
title = "Extraction of phenolic compounds from black mustard (Brassica nigra L.) seed by deep eutectic solvents",
pages = "1938-1931",
number = "2",
volume = "15",
doi = "10.1007/s11694-020-00772-y"
}
Đorđević, B. S., Todorović, Z. B., Troter, D. Z., Stanojević, L. P., Stojanović, G. S., Đalović, I., Mitrović, P.,& Veljković, V. B.. (2021). Extraction of phenolic compounds from black mustard (Brassica nigra L.) seed by deep eutectic solvents. in Journal of Food Measurement & Characterization
Springer, New York., 15(2), 1931-1938.
https://doi.org/10.1007/s11694-020-00772-y
Đorđević BS, Todorović ZB, Troter DZ, Stanojević LP, Stojanović GS, Đalović I, Mitrović P, Veljković VB. Extraction of phenolic compounds from black mustard (Brassica nigra L.) seed by deep eutectic solvents. in Journal of Food Measurement & Characterization. 2021;15(2):1931-1938.
doi:10.1007/s11694-020-00772-y .
Đorđević, Biljana S., Todorović, Zoran B., Troter, Dragan Z., Stanojević, Ljiljana P., Stojanović, Gordana S., Đalović, Ivica, Mitrović, Petar, Veljković, Vlada B., "Extraction of phenolic compounds from black mustard (Brassica nigra L.) seed by deep eutectic solvents" in Journal of Food Measurement & Characterization, 15, no. 2 (2021):1931-1938,
https://doi.org/10.1007/s11694-020-00772-y . .
14
4
13

White Mustard (Sinapis alba L.) Oil in Biodiesel Production: A Review

Mitrović, Petar; Stamenković, Olivera S.; Banković-Ilić, Ivana B.; Đalović, Ivica; Njezić, Zvonko B.; Farooq, Muhammad; Siddique, Kadambot H. M.; Veljković, Vlada B.

(Frontiers Media Sa, Lausanne, 2020)

TY  - JOUR
AU  - Mitrović, Petar
AU  - Stamenković, Olivera S.
AU  - Banković-Ilić, Ivana B.
AU  - Đalović, Ivica
AU  - Njezić, Zvonko B.
AU  - Farooq, Muhammad
AU  - Siddique, Kadambot H. M.
AU  - Veljković, Vlada B.
PY  - 2020
UR  - http://fiver.ifvcns.rs/handle/123456789/2064
AB  - White mustard (Sinapis alba L.) seed oil is used for cooking, food preservation, body and hair revitalization, biodiesel production, and as a diesel fuel additive and alternative biofuel. This review focuses on biodiesel production from white mustard seed oil as a feedstock. The review starts by outlining the botany and cultivation of white mustard plants, seed harvest, drying and storage, and seed oil composition and properties. This is followed by white mustard seed pretreatments (shelling, preheating, and grinding) and processing techniques for oil recovery (pressing, solvent extraction, and steam distillation) from whole seeds, ground seed or kernels, and press cake. Novel technologies, such as aqueous, enzyme-assisted aqueous, supercritical CO2, and ultrasound-assisted solvent extraction, are also discussed. The main part of the review considers biodiesel production from white mustard seed oil, including fuel properties and performance. The economic, environmental, social, and human health risk/toxicological impacts of white mustard-based biodiesel production and use are also discussed.
PB  - Frontiers Media Sa, Lausanne
T2  - Frontiers in Plant Science
T1  - White Mustard (Sinapis alba L.) Oil in Biodiesel Production: A Review
VL  - 11
DO  - 10.3389/fpls.2020.00299
ER  - 
@article{
author = "Mitrović, Petar and Stamenković, Olivera S. and Banković-Ilić, Ivana B. and Đalović, Ivica and Njezić, Zvonko B. and Farooq, Muhammad and Siddique, Kadambot H. M. and Veljković, Vlada B.",
year = "2020",
abstract = "White mustard (Sinapis alba L.) seed oil is used for cooking, food preservation, body and hair revitalization, biodiesel production, and as a diesel fuel additive and alternative biofuel. This review focuses on biodiesel production from white mustard seed oil as a feedstock. The review starts by outlining the botany and cultivation of white mustard plants, seed harvest, drying and storage, and seed oil composition and properties. This is followed by white mustard seed pretreatments (shelling, preheating, and grinding) and processing techniques for oil recovery (pressing, solvent extraction, and steam distillation) from whole seeds, ground seed or kernels, and press cake. Novel technologies, such as aqueous, enzyme-assisted aqueous, supercritical CO2, and ultrasound-assisted solvent extraction, are also discussed. The main part of the review considers biodiesel production from white mustard seed oil, including fuel properties and performance. The economic, environmental, social, and human health risk/toxicological impacts of white mustard-based biodiesel production and use are also discussed.",
publisher = "Frontiers Media Sa, Lausanne",
journal = "Frontiers in Plant Science",
title = "White Mustard (Sinapis alba L.) Oil in Biodiesel Production: A Review",
volume = "11",
doi = "10.3389/fpls.2020.00299"
}
Mitrović, P., Stamenković, O. S., Banković-Ilić, I. B., Đalović, I., Njezić, Z. B., Farooq, M., Siddique, K. H. M.,& Veljković, V. B.. (2020). White Mustard (Sinapis alba L.) Oil in Biodiesel Production: A Review. in Frontiers in Plant Science
Frontiers Media Sa, Lausanne., 11.
https://doi.org/10.3389/fpls.2020.00299
Mitrović P, Stamenković OS, Banković-Ilić IB, Đalović I, Njezić ZB, Farooq M, Siddique KHM, Veljković VB. White Mustard (Sinapis alba L.) Oil in Biodiesel Production: A Review. in Frontiers in Plant Science. 2020;11.
doi:10.3389/fpls.2020.00299 .
Mitrović, Petar, Stamenković, Olivera S., Banković-Ilić, Ivana B., Đalović, Ivica, Njezić, Zvonko B., Farooq, Muhammad, Siddique, Kadambot H. M., Veljković, Vlada B., "White Mustard (Sinapis alba L.) Oil in Biodiesel Production: A Review" in Frontiers in Plant Science, 11 (2020),
https://doi.org/10.3389/fpls.2020.00299 . .
2
37
6
37

The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil

Đorđević, Biljana S.; Troter, Dragan Z.; Todorović, Zoran B.; Đalović, Ivica; Stanojević, Ljiljana P.; Mitrović, Petar; Veljković, Vlada B.

(Springer, New York, 2020)

TY  - JOUR
AU  - Đorđević, Biljana S.
AU  - Troter, Dragan Z.
AU  - Todorović, Zoran B.
AU  - Đalović, Ivica
AU  - Stanojević, Ljiljana P.
AU  - Mitrović, Petar
AU  - Veljković, Vlada B.
PY  - 2020
UR  - http://fiver.ifvcns.rs/handle/123456789/1971
AB  - This study reports the yields, physicochemical properties, fatty acid compositions, and antioxidant activities of black mustard (Brassica nigraL.) seed oils extracted by cold pressing and the solvent extraction using different solvents (n-hexane, trichloroethylene, and a mixture of trichloroethylene and the triethanolamine:glycerol deep eutectic solvent (TEOA:G DES) with no or after pretreatment with the TEOA:G DES. Density (0.9791 +/- 0.0003-0.9851 +/- 0.0003 g/cm(3)), viscosity (121.15 +/- 1.62-123.32 +/- 0.10 mPas), boiling point (179-185 +/- 1 degrees C), refractive index (1.4692 +/- 0.0006-1.4758 +/- 0.0011), acid (2.08 +/- 0.19-3.22 +/- 0.15 mg KOH/g), iodine (99.2 +/- 1.6-105.4 +/- 1.5 g I-2/100 g), peroxide (1.68 +/- 0.01-1.82 +/- 0.03 mmol O-2/kg), and saponification values (165.1 +/- 2.7-169.4 +/- 2.3 mg KOH/g), fatty acid composition and antioxidant activity of the extracted oil were determined in order to evaluate its potential use as a foodstuff, a pharmaceutical or a feedstock for biodiesel production. Although the maceration of black mustard seeds with sole trichloroethylene yielded the highest oil yield of 31.10 +/- 0.42 g/100 g, it required almost twice the volume of trichloroethylene compared to the volume applied in the macerations after the pre-treatment with the TEOA:G DES and with the mixture of trichloroethylene/TEOA:G DES. The oil extracted by the extraction in the presence of TEOA:G DES has similar physicochemical properties but better antioxidant activity than the oil extracted by cold pressing.
PB  - Springer, New York
T2  - Journal of Food Measurement & Characterization
T1  - The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil
EP  - 2577
IS  - 5
SP  - 2570
VL  - 14
DO  - 10.1007/s11694-020-00503-3
ER  - 
@article{
author = "Đorđević, Biljana S. and Troter, Dragan Z. and Todorović, Zoran B. and Đalović, Ivica and Stanojević, Ljiljana P. and Mitrović, Petar and Veljković, Vlada B.",
year = "2020",
abstract = "This study reports the yields, physicochemical properties, fatty acid compositions, and antioxidant activities of black mustard (Brassica nigraL.) seed oils extracted by cold pressing and the solvent extraction using different solvents (n-hexane, trichloroethylene, and a mixture of trichloroethylene and the triethanolamine:glycerol deep eutectic solvent (TEOA:G DES) with no or after pretreatment with the TEOA:G DES. Density (0.9791 +/- 0.0003-0.9851 +/- 0.0003 g/cm(3)), viscosity (121.15 +/- 1.62-123.32 +/- 0.10 mPas), boiling point (179-185 +/- 1 degrees C), refractive index (1.4692 +/- 0.0006-1.4758 +/- 0.0011), acid (2.08 +/- 0.19-3.22 +/- 0.15 mg KOH/g), iodine (99.2 +/- 1.6-105.4 +/- 1.5 g I-2/100 g), peroxide (1.68 +/- 0.01-1.82 +/- 0.03 mmol O-2/kg), and saponification values (165.1 +/- 2.7-169.4 +/- 2.3 mg KOH/g), fatty acid composition and antioxidant activity of the extracted oil were determined in order to evaluate its potential use as a foodstuff, a pharmaceutical or a feedstock for biodiesel production. Although the maceration of black mustard seeds with sole trichloroethylene yielded the highest oil yield of 31.10 +/- 0.42 g/100 g, it required almost twice the volume of trichloroethylene compared to the volume applied in the macerations after the pre-treatment with the TEOA:G DES and with the mixture of trichloroethylene/TEOA:G DES. The oil extracted by the extraction in the presence of TEOA:G DES has similar physicochemical properties but better antioxidant activity than the oil extracted by cold pressing.",
publisher = "Springer, New York",
journal = "Journal of Food Measurement & Characterization",
title = "The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil",
pages = "2577-2570",
number = "5",
volume = "14",
doi = "10.1007/s11694-020-00503-3"
}
Đorđević, B. S., Troter, D. Z., Todorović, Z. B., Đalović, I., Stanojević, L. P., Mitrović, P.,& Veljković, V. B.. (2020). The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil. in Journal of Food Measurement & Characterization
Springer, New York., 14(5), 2570-2577.
https://doi.org/10.1007/s11694-020-00503-3
Đorđević BS, Troter DZ, Todorović ZB, Đalović I, Stanojević LP, Mitrović P, Veljković VB. The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil. in Journal of Food Measurement & Characterization. 2020;14(5):2570-2577.
doi:10.1007/s11694-020-00503-3 .
Đorđević, Biljana S., Troter, Dragan Z., Todorović, Zoran B., Đalović, Ivica, Stanojević, Ljiljana P., Mitrović, Petar, Veljković, Vlada B., "The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard (Brassica nigraL.) seed oil" in Journal of Food Measurement & Characterization, 14, no. 5 (2020):2570-2577,
https://doi.org/10.1007/s11694-020-00503-3 . .
4
1
4

Production of biofuels from sorghum

Stamenković, Olivera S.; Siliveru, Kaliramesh; Veljković, Vlada B.; Banković-Ilić, Ivana B.; Tasić, Marija B.; Ciampitti, Ignacio A.; Đalović, Ivica; Mitrović, Petar; Sikora, Vladimir; Prasad, P. V. V.

(Pergamon-Elsevier Science Ltd, Oxford, 2020)

TY  - JOUR
AU  - Stamenković, Olivera S.
AU  - Siliveru, Kaliramesh
AU  - Veljković, Vlada B.
AU  - Banković-Ilić, Ivana B.
AU  - Tasić, Marija B.
AU  - Ciampitti, Ignacio A.
AU  - Đalović, Ivica
AU  - Mitrović, Petar
AU  - Sikora, Vladimir
AU  - Prasad, P. V. V.
PY  - 2020
UR  - http://fiver.ifvcns.rs/handle/123456789/1963
AB  - Sorghum is an important crop that serve multiple purposes as human food, animal feed, and bioenergy production. There are opportunities to produce different types of biofuels from sorghum-based biomass. Sorghum with its vast genetic resources can serve as bioenergy crop and not compete against the value of it as food and nutritional security crop. Bioenegy crops provides an opportunity for agriculture to be part of solution for energy and mitigation to climate change. This review provides detailed overview and current knowledge on the conversion of sorghum biomass (stalks, leaves, and grains) into liquid (bioethanol, biodiesel, and bio-oil), gas (biohydrogen, biogas, and syngas) and solid (biochar) biofuels. Progress made in the different sorghum-based biomass pretreatment and conversion processes including chemical, biochemical, thermochemical and biological processes (e.g. saccharification, fermentation, transesterification, hydrothermal liquefaction, pyrolysis, and gasification) are highlighted and described. In addition, several value-added products from sorghum gaining importance in biofuels production are summarized. Finally, the potential outlook on sorghum based biorefiners and potential for improving sorghum-based biofuel production is presented and discussed. The biorefinery concept offers a considerable scope for optimization of sorghum biomass utilization to produce biofuels and biochemicals. However, there is further need to clearly identify the best methods of pre-treatment, processing, and products from different sources. Sorghum with its high biomass production and multiple use has the potential to be key biofuel crop. Further research is needed to identify most efficient and cost effective processes to ensure the value of biofuel and other bioproducts from sorghum. A complete lifecycle analyses indicating the challenges and opportunities to enhance the efficiency, benefits, and challenges in different steps and finding solutions to overcome those challenges will be of prime importance. Strong collaboration between private and public sector researhcers and multidisciplinary teams will be required to develop a comprehensive biorefinery models.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Renewable & Sustainable Energy Reviews
T1  - Production of biofuels from sorghum
VL  - 124
DO  - 10.1016/j.rser.2020.109769
ER  - 
@article{
author = "Stamenković, Olivera S. and Siliveru, Kaliramesh and Veljković, Vlada B. and Banković-Ilić, Ivana B. and Tasić, Marija B. and Ciampitti, Ignacio A. and Đalović, Ivica and Mitrović, Petar and Sikora, Vladimir and Prasad, P. V. V.",
year = "2020",
abstract = "Sorghum is an important crop that serve multiple purposes as human food, animal feed, and bioenergy production. There are opportunities to produce different types of biofuels from sorghum-based biomass. Sorghum with its vast genetic resources can serve as bioenergy crop and not compete against the value of it as food and nutritional security crop. Bioenegy crops provides an opportunity for agriculture to be part of solution for energy and mitigation to climate change. This review provides detailed overview and current knowledge on the conversion of sorghum biomass (stalks, leaves, and grains) into liquid (bioethanol, biodiesel, and bio-oil), gas (biohydrogen, biogas, and syngas) and solid (biochar) biofuels. Progress made in the different sorghum-based biomass pretreatment and conversion processes including chemical, biochemical, thermochemical and biological processes (e.g. saccharification, fermentation, transesterification, hydrothermal liquefaction, pyrolysis, and gasification) are highlighted and described. In addition, several value-added products from sorghum gaining importance in biofuels production are summarized. Finally, the potential outlook on sorghum based biorefiners and potential for improving sorghum-based biofuel production is presented and discussed. The biorefinery concept offers a considerable scope for optimization of sorghum biomass utilization to produce biofuels and biochemicals. However, there is further need to clearly identify the best methods of pre-treatment, processing, and products from different sources. Sorghum with its high biomass production and multiple use has the potential to be key biofuel crop. Further research is needed to identify most efficient and cost effective processes to ensure the value of biofuel and other bioproducts from sorghum. A complete lifecycle analyses indicating the challenges and opportunities to enhance the efficiency, benefits, and challenges in different steps and finding solutions to overcome those challenges will be of prime importance. Strong collaboration between private and public sector researhcers and multidisciplinary teams will be required to develop a comprehensive biorefinery models.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Renewable & Sustainable Energy Reviews",
title = "Production of biofuels from sorghum",
volume = "124",
doi = "10.1016/j.rser.2020.109769"
}
Stamenković, O. S., Siliveru, K., Veljković, V. B., Banković-Ilić, I. B., Tasić, M. B., Ciampitti, I. A., Đalović, I., Mitrović, P., Sikora, V.,& Prasad, P. V. V.. (2020). Production of biofuels from sorghum. in Renewable & Sustainable Energy Reviews
Pergamon-Elsevier Science Ltd, Oxford., 124.
https://doi.org/10.1016/j.rser.2020.109769
Stamenković OS, Siliveru K, Veljković VB, Banković-Ilić IB, Tasić MB, Ciampitti IA, Đalović I, Mitrović P, Sikora V, Prasad PVV. Production of biofuels from sorghum. in Renewable & Sustainable Energy Reviews. 2020;124.
doi:10.1016/j.rser.2020.109769 .
Stamenković, Olivera S., Siliveru, Kaliramesh, Veljković, Vlada B., Banković-Ilić, Ivana B., Tasić, Marija B., Ciampitti, Ignacio A., Đalović, Ivica, Mitrović, Petar, Sikora, Vladimir, Prasad, P. V. V., "Production of biofuels from sorghum" in Renewable & Sustainable Energy Reviews, 124 (2020),
https://doi.org/10.1016/j.rser.2020.109769 . .
8
98
21
88